WebAn asymmetric synthesis of solenopsin A. Tetrahedron Letters 1994, 35 (6) , 829-832. DOI: 10.1016/S0040-4039(00)75974-0. Charles W. Jefford, Bo Wang Jian. An enantiospecific synthesis of solenopsin A. Tetrahedron Letters 1993, 34 (18) , 2911 WebIn a recent publication3 we described the preparation of the (-)-2-cyano-6-oxazolopiperidine synthon 4, a new chiral 1,Cdihydropyridine equivalent, and showed that selective …
Euglenophycin - Wikipedia
WebJan 1, 1982 · Methods and selectivities for previous syntheses of solenopsin A: a) Reduction of 2, 6-disubstituted pyridine with sodium in ethanol (cis/trans = 85:15).5a b) Mundy N-acyllactam rearrangement followed by reduction of the imine with NaBH4 (cis/trans = 80:20).5b c) Nitrosation, equilibrium by t-BuOK, and denitrosation of the cis … WebJan 20, 2024 · Synthesis of (+)-solenopsin, a 2,6-disubstituted piperidine alkaloid, isolated from fire ants (Solenopsis), was achieved. Stereoselective construction of trans -2,6 … sigmatech inc
An enantiospecific synthesis of solenopsin A Semantic Scholar
WebTherefore, solenopsin and related compounds have been the target of organic synthesis from which pure compounds can be produced for individual study. Originally synthesized in 1993, several groups have designed novel and creative methods of synthesizing enantiopure solenopsin and other alkaloidal components of ant venom. WebNational Center for Biotechnology Information WebAn enantiospecific synthesis of solenopsin A @article{Jefford1993AnES, title={An enantiospecific synthesis of solenopsin A}, author={Charles W. Jefford and Bo Wang Jian}, journal={Tetrahedron Letters}, year={1993}, volume={34}, pages={2911-2914} } C. W. Jefford, B. Jian; Published 30 April 1993; ... sigmatech essential brush set